"Steric and Electronic Effects on the Reactivity of Rh and Ir Complexes Containing P-S, P-P and P-O Ligands; Implications for the Effects of Chelate Ligands in Catalysis"
L. Gonsalvi, H. Adams, G. J. Sunley, E. Ditzel and A. Haynes
J. Am. Chem. Soc., 2002, 124, 13597  


Rotatable x-ray structures (Jmol)

[Ir(CO)(dppms)I₂Me]

[Ir(CO)(dppms)I₂Et]

[Ir(CO)(dppms)IMe]₂(OTf)₂ (triflate counterions omitted)

[Rh(dppms)I₂(COMe)]

[Rh(dppe)I₂(COMe)]

[Rh(dppmo)(NCMe)I₂(COMe)]

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