"Promotion of Iridium Catalyzed Methanol Carbonylation: Mechanistic Studies of the Cativa Process"
A. Haynes, P. M. Maitlis, G. E. Morris, G. J. Sunley, H. Adams, P. W. Badger, C. M. Bowers, D. B. Cook, P. I. P. Elliott, T. Ghaffar, H. Green, T. R. Griffin, M. Payne, J. M. Pearson, M. J. Taylor, P. W. Vickers and R. J. Watt
J. Am. Chem. Soc., 2004, 126, 2847
Rotatable x-ray structures (Jmol)

[Ir(CO)₂(COMe)I₃]^- (Ph₄As⁺ counter-ion omitted)

[Ir(CO)₂I₂Me]₂

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