"Ligand stereoelectronic effects in complexes of phospholanes, phosphinanes and phosphepanes and their implications for hydroformylation catalysis"
R. A. Baber, M. F. Haddow, A. J. Middleton, A. G. Orpen, P. G. Pringle, A. Haynes, G. L. Williams and R. Papp
Organometallics, 2007, 26, 713


Rotatable x-ray structures (Jmol)

cis-[PtCl₂(P(CH₂)₄Ph)₂]

cis-[PtCl₂(P(CH₂)₅Ph)₂]

cis-[PtCl₂(P(CH₂)₆Ph)₂]

cis-[PtCl₂(P(CH₂)₅^tBu)₂]

trans-[PtCl₂(P(CH₂)₅^tBu)₂]

trans-[PtI₂(P(CH₂)₅Ph)₂]

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