Dr. Anthony Haynes
Department of Chemistry, University of Sheffield
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"Identification of the Reactive
cis,mer
Isomer of [Ir(CO)
2
I
3
Me]
-
; Relation to the Mechanism of Iridium-Catalyzed Methanol Carbonylation"
A. Haynes, A. J. H. M. Meijer, J. R. Lyons and H. Adams
Inorg. Chem.
,
2009
,
48
, 28
Rotatable x-ray structures (Jsmol)
[{Ir(CO)I
3
Me}
2
][AsPh
4
]
2
[Me(CO)(I)Ir(μ-I)
2
(μ-OH)Ir(CO)(I)Me]AsPh
4
trans-[Ir(CO)
2
I
3
(COMe)][AsPh
4
]
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