"Mechanistic Study of Rhodium/Xantphos Catalyzed Methanol Carbonylation"
G. L. Williams, C. M. Parks, C. R. Smith, H. Adams, A. Haynes, A. J. H. M. Meijer, G. J. Sunley and S. Gaemers
Organometallics, 2011, 30, 6166

Rotatable x-ray structures (Jmol)

[Rh(xantphos)(COMe)I₂]

[{Rh(xantphos)(COMe)I(NCMe)]BF₄ (BF₄ counterion omitted)

[{Rh(xantphos)(COMe)(μ-I)}₂].2BF₄ (BF₄ counterions omitted)

[Rh(xantphos)(CO)Cl]

[Rh(o-tol-xantphos)(CO)Cl]

[Rh(o-tol-xantphos)(CO)I]

[Rh(o-tol-xantphos)(CO)]BF₄ (BF₄ counterion omitted)

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