"Mechanistic Study of Rhodium/Xantphos Catalyzed Methanol Carbonylation"
G. L. Williams, C. M. Parks, C. R. Smith, H. Adams, A. Haynes, A. J. H. M. Meijer, G. J. Sunley and S. Gaemers
Organometallics, 2011, 30, 6166

Rotatable x-ray structures (Jmol)

Test0
spin off

Test00
spin off



Test1
spin off



Test2
spin off









[Rh(xantphos)(COMe)I2]



[{Rh(xantphos)(COMe)I(NCMe)]BF4 (BF4 counterion omitted)



[{Rh(xantphos)(COMe)(μ-I)}2].2BF4 (BF4 counterions omitted)



[Rh(xantphos)(CO)Cl]



[Rh(o-tol-xantphos)(CO)Cl]



[Rh(o-tol-xantphos)(CO)I]



[Rh(o-tol-xantphos)(CO)]BF4 (BF4 counterion omitted)



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