"Mechanistic Study of Rhodium/Xantphos Catalyzed Methanol Carbonylation"
G. L. Williams, C. M. Parks, C. R. Smith, H. Adams, A. Haynes, A. J. H. M. Meijer, G. J. Sunley and S. Gaemers
Organometallics, 2011, 30, 6166
Rotatable x-ray structures (Jmol)
Test0
spin
off
Test00
spin
off
Test1
spin
off
Test2
spin
off
[Rh(xantphos)(COMe)I2]
[{Rh(xantphos)(COMe)I(NCMe)]BF4 (BF4 counterion omitted)
[{Rh(xantphos)(COMe)(μ-I)}2].2BF4 (BF4 counterions omitted)
[Rh(xantphos)(CO)Cl]
[Rh(o-tol-xantphos)(CO)Cl]
[Rh(o-tol-xantphos)(CO)I]
[Rh(o-tol-xantphos)(CO)]BF4 (BF4 counterion omitted)
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