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"Mechanistic Study of Rhodium/Xantphos Catalyzed Methanol Carbonylation"
G. L. Williams, C. M. Parks, C. R. Smith, H. Adams, A. Haynes, A. J. H. M. Meijer, G. J. Sunley and S. Gaemers
Organometallics, 2011, 30, 6166
Rotatable x-ray structures (Jsmol)
[Rh(xantphos)(COMe)I2]
[{Rh(xantphos)(COMe)I(NCMe)]BF4 (BF4 counterion omitted)
[{Rh(xantphos)(COMe)(μ-I)}2].2BF4 (BF4 counterions omitted)
[Rh(xantphos)(CO)Cl]
[Rh(o-tol-xantphos)(CO)Cl]
[Rh(o-tol-xantphos)(CO)I]
[Rh(o-tol-xantphos)(CO)]BF4 (BF4 counterion omitted)
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